Abstract
The Xixia amber is the largest known Mesozoic amber deposit in China to date. Here we analyse amber collected over the years from 12 localities in the Upper Cretaceous Gaogou Formation in Xixia, Henan, including physical property tests and Fourier transform infrared spectroscopy (FT-IR) analysis. The main preservation forms of the Xixia amber include nest-like, vein-like, and layered irregular shapes, as well as gravel-like forms resulting from secondary transportation. Recent discoveries include numerous small-grained amber specimens preserved in grey-black silty shale rich in plant debris, suggesting a near-in-situ depositional environment. The Xixia Basin’s Late Cretaceous strata are renowned for their abundance in dinosaur eggs. In-depth research on the Xixia amber will help to understand the geological history and ecosystem evolution of the Xixia Basin during the Late Cretaceous, as well as the global distribution characteristics of Cretaceous amber.
References
- Azar, D., Gèze, R. & Acra, F. (2010) Chapter 14: Lebanese amber. In: Penney, D. (Ed.), Biodiversity of fossils in amber from the major World deposits. Siri Scientific Press, Manchester, pp. 271–298.
- Azar, D., Maksoud, S., Cai, C.Y. & Huang, D.Y. (2019) A new amber outcrop from the Lower Cretaceous of northeastern China. Palaeoentomology, 2 (4), 345–349. https://doi.org/10.11646/palaeoentomology.2.4.8
- Cao, M.Z. & Wang, D.Y. (2011) Late Cretaceous non-marine Ostracoda from the dinosaur egg-bearing strata of Xixia basin, Henan, China. Acta Palaeontologica Sinca, 46 (3), 299–313. [In Chinese]
- Chai, Y. & Huang, B. (2011) The behavior of thermal variation about the emperor from Xixia, Henan. Superhard Material Engineering, 23 (1), 56–61. [In Chinese]
- Chen, J.H., Wang, D.Y., Feng, J.C., Fu, G.H. & Zhu, S.G. (2007) Late Cretaceous non-marine bivalves from the dinosaur egg-bearing strata of Xixia basin, Henan, China. Acta Palaeontologica Sinca, 46 (3), 299–313. [In Chinese]
- Delclòs, X., Peñalver, E., Barrón, E., Peris, D., Grimaldi, D.A., Holz, M., Labandeira, C.C., Saupe, E.E., Scotese, C.R., Solórzano-Kraemer, M.M., Álvarez-Parra, S., Arillo, A., Azar, D., Cadena, E.A., Corso, J.D., Kvaček, J., MonleónGetino, A., Nel, A., Peyrot, D., Bueno-Cebollada, C.A., Gallardo, A., González-Fernández, B., Goula, M., Jaramillo, C., Kania-Kłosok, L., Valle, R.L., Lozano, R P., Meléndez, N., Menor-Salván, C., Peña-Kairath, C., Perrichot, V., Rodrigo, A., Sánchez-García, A., Santer, M., Sarto i Monteys, V., Uhl, D., Viejo, J.L. & Pérez-de la Fuente, R. (2023) Amber and the Cretaceous resinous interval. Earth-Science Reviews, 243, 104486. https://doi.org/10.1016/j.earscirev.2023.104486
- Gao, H.L., Su, Y.T., Cai, C.Y. Azar, D., Song, X.B., Lian, X.N. & Huang, D.Y. (2024) Discussion on the age of the Early Cretaceous amber from the Hailar Basin, NE China. Mesozoic, 1 (2), 192–207. https://doi.org/10.11646/mesozoic.1.2.11
- He, Q., Yang, S., Jia, S.H., Xu, L., Xing, L.D., Gao, D.S., Liu, D., Gao, Y.L. & Zheng, Y.L. (2020) Trace element and isotope geochemistry of macroelongatoolithid eggs as an indicator of palaeoenvironmental reconstruction from the Late Cretaceous Xixia Basin, China. Cretaceous Research, 109, 104373. https://doi.org/10.1016/j.cretres.2020.104373
- Henan Provincial Bureau of Geology and Mineral Resources. (1997) Lithologic stratigraphy of Henan Province. China University of Geosciences Press, Wuhan, 299 pp. [In Chinese]
- Li, Y.F., Cai H.A., Liang, H.D., Zhang, J., Mei, Y.Q. & Zhang, H.G. (2006) A study on the macro mineral compositions of the dinosaur egg fossils in the Late Cretaceous collected from Xixia Basin, Henan Province. Journal of Jilin University (Earth Science Edition), 36 (2), 158–163+168. [In Chinese] https://doi.org/10.13278/j.cnki.jjuese.2006.02.002
- Li, Y., Feng, Y.L., Du, J.F., Wang, Y.M., Shi, G.H. & Liang, Y.Z. (2024) Spectral and chemical characterization of amber from Xixia, Henan Province, China via FTIR, three-dimensional fluorescence spectra and Py (HMDS)-GC-MS. Heliyon, 10 (16), e35066. https://doi.org/10.1016/j.heliyon.2024.e35066
- Li, Y.L., Zheng, D.R., Sha, J.G., Zhang, H.C., Denyszyn, S. & Chang, S.C. (2023) Lower Cretaceous Hailar amber: The oldest-known amber from China. Cretaceous Research, 145, 105472. https://doi.org/10.1016/j.cretres.2022.105472
- Ni, Z.J., Song, X.B., Azar, D., Wang, Z.X., Cai, C.Y., Xuan, Q., Maksoud, S., Lian, X.N. & Huang, D.Y. (2023) Discovery of Late Cretaceous amber from Guangzhou, South China. Palaeoentomology, 6 (4), 329–332. https://doi.org/10.11646/palaeoentomology.6.4.3
- Shi, G.L., Dutta, S., Paul, S., Wang, B. & Jacques, F.M.B. (2014) Terpenoid compositions and botanical origins of Late Cretaceous and Miocene amber from China. PLoS One, 9 (10), e111303. https://doi.org/10.1371/journal.pone.0111303
- Song, X.B., Sui, X., Xuan, Q., Azar D., Cai, C.Y., Wang Z.X. & Huang D.Y. (2024) A new amber outcrop from the Late Cretaceous of Xingning Basin, South China. Palaeoentomology, 7 (6), 770–777. https://doi.org/10.11646/palaeoentomology.7.6.12
- Wang, B., Rust, J., Engel, M.S., Szwedo, J., Dutta, S., Nel, A., Fan, Y., Meng, F.W., Shi, G.L., Jarzembowski, E.A., Wappler, T., Stebner, F., Fang, Y., Mao, L.M., Zheng, D.R. & Zhang, H.C. (2014) A diverse paleobiota in Early Eocene Fushun amber from China. Current Biology, 24 (14), 1606–1610. https://doi.org/10.1016/j.cub.2014.05.048
- Wang, B., Shi, G.L., Xu, C.P. Spicer, R.A., Perrichot, V., Schmidt, A.R., Feldberg, K., Heinrichs, J., Chény, C., Pang, H., Liu, X.Y., Gao, T.P., Wang, Z.X., Ślipiński, A., Solórzano-Kraemer, M.M., Heads, S.W., Thomas, M.J., Sadowski, E.M., Szwedo, J., Azar, D., Nel, A., Liu, Y., Chen, J., Zhang, Q., Zhang, Q.Q., Luo, C.H., Yu, T.T., Zheng, D.R., Zhang, H.C. & Engel, M.S. (2021) The mid-Miocene Zhangpu biota reveals an outstandingly rich rainforest biome in East Asia. Science Advances, 7, eabg0625. https://doi.org/10.1126/sciadv.abg0625
- Wang, D.Y., Feng, J.C., Zhu, S.G., Wu, M., Fu, G.H., He, P., Qiao, G.C., Pang, J.F., Li, G.W., Li, B.X., Li, J., Wang, B.X., Zhang, G.J., Qin, Z. & Guo, G.L. (2008) The dinosaur eggs and dinosaur fossils in Henan Province, China. Geology Press, Beijing, 320 pp. [In Chinese]
- Wang, H.S. (1989) A mineralogical study of Amber from Xixia region, Hennan province. Acta Mineralogica Sinica, 9 (4), 338–344+387. [In Chinese] https://doi.org/10.16461/j.cnki.1000-4734.1989.04.008
- Wang, X.L., Wang, Q., Jiang, S.X., Cheng, X., Zhang, J.L., Zhao, Z.K. & Jiang, Y.G. (2012) Dinosaur egg faunas of the Upper Cretaceous terrestrial red beds of China and their stratigraphical significance. Journal of Stratigraphy, 36 (2), 400–416. https://doi.org/10.19839/j.cnki.dcxzz.2012.02.017
- Wang, X.W., Yao, X.Y. & Xu, X.Y. (2015) Trace element determination of Late Cretaceous dinosaur eggshell fossils from Xixia Basin, Henan Province by ICP-OES and Its Implications for Extinction of Dinosaurs. Rock and Mineral Analysis, 34 (5), 520–527. [In Chinese] https://doi.org/10.15898/j.cnki.11-2131/td.2015.05.004
- Yang, W.R. (1987) "Opening" and "closing" history in east Qinling era. Earth Science, 12 (5), 487–493. [In Chinese]
- Zhang, Y.G. & Pei, J. (2004) Trace element combinations in Upper Cretaceous dinosaur egg fossils from Xixia Basin and discussion on paleoclimate. Acta Palaeontologica Sinica, 43 (2), 297–302. [In Chinese]
- Zhong, H.B. (2003) Amber resources of China. Journal of Gems and Gemmology, 5 (2), 33. [In Chinese] https://doi.org/10.15964/j.cnki.027jgg.2003.02.012
- Zhou, S.Q. & Zhao, S.L. (2005) Initial study on the Xixia-Neixiang amber deposit of Henan. Mineral Resources and Geology, 19, 57–59. [In Chinese]
- Zhou, S.Q., Feng Z.J. & Hui Y.X. (2001) A study of dinosaur and fossil eggs from the Xixia Basin, Henan. Jiangxi Geology, 15 (2), 96–101. [In Chinese]
- Zhou, S.Q., Han, S.J. & Zhang, Y.C. (1983) The Late Cretaceous strata from Xixia Basin, Henan Province. Journal of Stratigraphy, 7 (1), 64–70. [In Chinese]
- Zhu, G.Y. (1997) Stratigraphy and sedimentary facies of red beds in Xixia Basin of Henan Province. Journal of the University of Petroleum, China, 21 (6), 110–113+123. [In Chinese]